Search results for "High interest"
showing 9 items of 9 documents
Masonry structures: A proposal of analytical generation of fragility functions for tsunami impact – Application to the Mediterranean coasts
2021
Abstract Evaluation of tsunami vulnerability of coastal buildings is gaining high interest in recent years in the areas with high tsunami hazard. Fragility evaluation is a fundamental step to obtain a quantitative estimation of the probability of building damage and in order to define possible strategies for risk mitigation. Several empirical fragility curves are available for masonry structures. However, an empirical fragility curve is generally based on field surveys after tsunami events, not always available. Conversely, analytical fragility curves are based on prediction approaches. In this paper, a proposal for the evaluation of analytical fragility curves for masonry structures typica…
Considerations Regarding the Analysis and Interpretation of Traumatic Lesional Mechanisms in Road Accidents
2021
According to statistics, road transportation is the most dangerous means of transportation and also the costliest in terms of human lives and material damage. The increase of road safety is a priority goal of the European Commission and an area of high interest for Romania, which is unfortunately placed very high in the hierarchy of countries with a high number of deaths resulting from road accidents. This study presents the mechanisms of the generation of traumatic injuries and also analyses the manner of interpreting these mechanisms in the case of road accidents, both from the perspective of law enforcement and from the perspective of specialists in road transportation, who analyse and i…
Electrochemical formation of N,N′-diarylhydrazines by dehydrogenative N–N homocoupling reaction
2020
Hydrazines represent a class of compounds of high interest due to their applicability as versatile starting materials in many important transformations. Herein, we report a synthetic approach to hydrazine derivatives using commercially available anilines and an anodic dehydrogenative N-N coupling reaction as the key step.
Current trends on the determination of organic UV filters in environmental water samples based on microextraction techniques – A review
2018
UV filters are a group of cosmetic ingredients commonly used in a wide variety of cosmetic products to protect users from UV solar radiation. They belong to different chemical families, such as benzophenones, p-aminobenzoates, salicylates, cinnamates, benzotriazoles, benzimidazoles, camphor derivatives, triazines, etc. These cosmetic ingredients are considered as emerging contaminants since they easily reach the aquatic environment, where they are accumulated causing harmful effects in the flora and fauna despite being present at the ng L-1 level. Therefore, the development of sensitive and selective analytical methods for their environmental surveillance monitoring is of high interest. In …
Use of Nanomaterial-Based (Micro)Extraction Techniques for the Determination of Cosmetic-Related Compounds
2020
The high consumer demand for cosmetic products has caused the authorities and the industry to require rigorous analytical controls to assure their safety and efficacy. Thus, the determination of prohibited compounds that could be present at trace level due to unintended causes is increasingly important. Furthermore, some cosmetic ingredients can be percutaneously absorbed, further metabolized and eventually excreted or bioaccumulated. Either the parent compound and/or their metabolites can cause adverse health effects even at trace level. Moreover, due to the increasing use of cosmetics, some of their ingredients have reached the environment, where they are accumulated causing harmful effec…
Ultrathin silicon nanowires for optical and electrical nitrogen dioxide detection
2021
The ever-stronger attention paid to enhancing safety in the workplace has led to novel sensor development and improvement. Despite the technological progress, nanostructured sensors are not being commercially transferred due to expensive and non-microelectronic compatible materials and processing approaches. In this paper, the realization of a cost-effective sensor based on ultrathin silicon nanowires (Si NWs) for the detection of nitrogen dioxide (NO2) is reported. A modification of the metal-assisted chemical etching method allows light-emitting silicon nanowires to be obtained through a fast, low-cost, and industrially compatible approach. NO2 is a well-known dangerous gas that, even wit…
Results of the NA31 Experiment on K0Decays
1989
Decays of neutral kaons are of high interest in high energy physics. The discovery of CP violation1 opened up a field of new physics. Today, interest is concentrated on precision measurements of CP-violating parameters as well as on searches for rare decays that are suppressed or forbidden in the standard model.
Peptide-Controlled Assembly of Macroscopic Calcium Oxalate Nanosheets
2019
The fabrication of two-dimensional (2D) biomineral nanosheets is of high interest owing to their promise for applications in electronics, filtration, catalysis, and chemical sensing. Using a facile approach inspired by biomineralization in nature, we fabricate laterally macroscopic calcium oxalate nanosheets using β-folded peptides. The template peptides are composed of repetitive glutamic acid and leucine amino acids, self-organized at the air-water interface. Surface-specific sum frequency generation spectroscopy and molecular dynamics simulations reveal that the formation of oxalate nanosheets relies on the peptide-Ca 2+ ion interaction at the interface, which not only restructures the …
ChemInform Abstract: Access to Pyrazolidin-3,5-diones Through Anodic N-N Bond Formation.
2016
Pyrazolidin-3,5-diones are important motifs in heterocyclic chemistry and are of high interest for pharmaceutical applications. In classic organic synthesis, the hydrazinic moiety is installed through condensation using the corresponding hydrazine building blocks. However, most N,N'-diaryl hydrazines are toxic and require upstream preparation owing to their low commercial availability. We present an alternative and sustainable synthetic approach to pyrazolidin-3,5-diones that employs readily accessible dianilides as precursors, which are anodically converted to furnish the N-N bond. The electroconversion is conducted in a simple undivided cell under constant-current conditions.